Microstructure-Erosion Resistance Correlation in High Chromium Cast Iron: A Digital Image Processing Approach

Authors

DOI:

https://doi.org/10.7494/jcme.2026.10.2.34-41

Keywords:

chromium-rich carbides, hardfacing, image analysis, solid particle erosion, microstructural characterisation

Abstract

High chromium cast irons (HCCIs) are widely employed as wear-resistant hardfacing materials in industrial applications where solid particle erosion (SPE) represents a primary degradation mechanism, such as in energy production, mining, and cement manufacturing. The erosive wear resistance of these alloys is strongly dependent on the microstructural features of the primary M7C3 carbides, particularly their size, morphology, and spatial distribution within the metallic matrix. The quantitative relationship between carbide distribution homogeneity and erosion resistance has received limited attention in the literature. This study investigates the erosive wear resistance of a Fe-Cr-C cast iron hardfacing alloy and proposes three digital image processing methods to quantitatively characterise the carbide microstructure and correlate it with experimental erosion test results. Optical microscopy combined with image binarisation was used to segment primary M7C3 carbides. Three methods were adopted: carbide volume fraction (CVF), minimum inter-carbide distances, and a moving scanning area approach. Erosion tests were conducted according to ASTM G76 guidelines using two Arizona road dust powder grades with two mean diameters under equal kinetic energy conditions. Results show that the erosion rate decreases significantly with the increasing erodent particle size and that carbide distribution homogeneity plays a critical role in determining the erosion resistance. The moving scanning area method proved particularly effective at correlating microstructural coverage with experimental erosion rates.

Downloads

Download data is not yet available.

References

[1] Tandon D., Li H., Pan Z., Yu D. & Pang W. (2023). A review on hardfacing, process variables, challenges, and future works. Metals, 13(9), 1512. DOI: https://doi.org/10.3390/met13091512.

[2] Badisch E. & Roy M. (2013). Hardfacing for Wear, Erosion and Abrasion. In: M. Roy (Ed.), Surface Engineering for Enhanced Performance against Wear (pp. 149–191). Vienna: Springer. DOI: https://doi.org/10.1007/978-3-7091-0101-8.

[3] Budinski K.G. & Budinski S.T. (2021). Tribomaterials: Properties and Selection for Friction, Wear, and Erosion Applications. ASM International. DOI: https://doi.org/10.31399/asm.tb.tpsfwea.9781627083232.

[4] Lin C.-M., Chang C.-M., Chen J.-H., Hsieh C.-C. & Wu W. (2009). Microstructural evolution of hypoeutectic, near-eutectic, and hypereutectic high-carbon Cr-based hard-facing alloys. Metallurgical and Materials Transactions A, 40, 1031–1038. DOI: https://doi.org/10.1007/s11661-009-9784-6.

[5] Wiengmoon A. (2011). Carbides in high chromium cast irons. Naresuan University Engineering Journal, 6(1), 64–71. DOI: https://doi.org/10.14456/nuej.2011.6.

[6] Li P., Yang Y., Shen D., Gong M., Tian C. & Tong W. (2020). Mechanical behavior and microstructure of hypereutectic high chromium cast iron: the combined effects of tungsten, manganese and molybdenum additions. Journal of Materials Research and Technology, 9(3), 5735–5748. DOI: https://doi.org/10.1016/j.jmrt.2020.03.098.

[7] Gaqi Y., Kusumoto K., Shimizu K. & Purba R.H. (2023). Effect of carbide orientation on wear characteristics of high-alloy wear-resistant cast irons. Lubricants, 11(7), 272. DOI: https://doi.org/10.3390/lubricants11070272.

[8] Liu S., Zhou Y., Xing X., Wang J., Ren X. & Yang Q. (2016). Growth characteristics of primary M7C3 carbide in hypereutectic Fe-Cr-C alloy. Scientific Reports, 6, 32941. DOI: https://doi.org/10.1038/srep32941.

[9] Rajicic B.M., Maslarevic A., Bakic G.M., Maksimovic V. & Djukic M.B. (2023). Erosion wear behavior of high chromium cast irons. Transactions of the Indian Institute of Metals, 76, 1427–1437. DOI: https://doi.org/10.1007/s12666-022-02860-7.

[10] Sapate S.G. & Rama Rao A.V. (2004). Effect of carbide volume fraction on erosive wear behaviour of hardfacing cast irons. Wear, 256(7–8), 774–786. DOI: https://doi.org/10.1016/S0043-1648(03)00527-1.

[11] Karantzalis A.E., Lekatou A. & Diavati E. (2009). Effect of destabilization heat treatments on the microstructure of high-chromium cast iron: A microscopy examination approach. Journal of Materials Engineering and Performance, 18, 1078–1085. DOI: https://doi.org/10.1007/s11665-009-9353-6.

[12] Jindal C., Singh Sidhu B., Kumar P. & Singh Sidhu H. (2022). Performance of hardfaced/heat treated materials under solid particle erosion: A systematic literature review. Materials Today: Proceedings, 50, 629–639. DOI: https://doi.org/ 10.1016/j.matpr.2021.03.441.

[13] Kibble K.A. & Pearce J.T.H. (1993). Influence of heat treatment on the microstructure and hardness of 19% high-chromium cast irons. Cast Metals, 6(1), 9–15. DOI: https://doi.org/10.1080/09534962.1993.11819121.

[14] Tarodiya R. & Levy A. (2021). Surface erosion due to particle-surface interactions – A review. Powder Technology, 387, 527–559. DOI: https://doi.org/10.1016/j.powtec.2021.04.055.

[15] Lindsley B.A. & Marder A.R. (1999). The effect of velocity on the solid particle erosion rate of alloys. Wear, 225–229 (Part 1), 510–516. DOI: https://doi.org/10.1016/S0043-1648(99)00085-X.

[16] Oka Y.I. & Yoshida T. (2005). Practical estimation of erosion damage caused by solid particle impact. Wear, 259(1–6), 102–109. DOI: https://doi.org/10.1016/j.wear.2005.01.040.

[17] Sapate S.G. & RamaRao A.V. (2006). Erosive wear behaviour of weld hardfacing high chromium cast irons: effect of erodent particles. Tribology International, 39(3), 206–212. DOI: https://doi.org/10.1016/j.triboint.2004.10.013.

[18] ASTM International. (2013). ASTM G76-07: Standard Test Method for Conducting Erosion Tests by Solid Particle Impingement Using Gas Jets. ASTM International.

[19] Fortini A., Suman A., Vulpio A., Merlin M. & Pinelli M. (2021). Microstructural and erosive wear characteristics of a high chromium cast iron. Coatings, 11(5), 490. DOI: https://doi.org/10.3390/coatings11050490.

[20] Fortini A., Suman A., Zanini N. & Cruciani G. (2022). Erosive wear behavior of high-chromium cast iron: combined effect of erodent powders and destabilization heat treatments. Coatings, 12(8), 1218. DOI: https://doi.org/10.3390/coatings12081218.

[21] Fortini A., Suman A. & Zanini N. (2023). An experimental and numerical study of the solid particle erosion damage in an industrial cement large-sized fan. Engineering Failure Analysis, 146, 107058. DOI: https://doi.org/10.1016/j.engfailanal.2023.107058.

[22] ISO 12103-1:2016. (2016). Road vehicles – Test contaminants for filter evaluation – Part 1: Arizona test dust. International Organization for Standardization.

[23] Schneider C.A., Rasband W.S. & Eliceiri K.W. (2012). NIH Image to ImageJ: 25 years of image analysis. Nature Methods, 9, 671–675. DOI: https://doi.org/10.1038/nmeth.2089.

Downloads

Published

2026-06-18

Issue

Section

Orginal Articles

How to Cite

Vezzani, O., Fortini, A., Gragnanini, M., Suman, A., & Zanini, N. (2026). Microstructure-Erosion Resistance Correlation in High Chromium Cast Iron: A Digital Image Processing Approach. Journal of Casting & Materials Engineering, 10(2), 34-41. https://doi.org/10.7494/jcme.2026.10.2.34-41