THE IMPACT OF TEMPERATURE ON FURAN RESIN AND BINDER STRUCTURE

Authors

  • Artur Bobrowski AGH University of Science and Technology, Faculty of Foundry Engineering, Kraków, Poland
  • Beata Grabowska AGH University of Science and Technology, Faculty of Foundry Engineering, Kraków, Poland

DOI:

https://doi.org/10.7494/mafe.2012.38.1.73

Keywords:

furan resins, furan binders, FTIR, ATR

Abstract

Exposure to high temperature causes a series of structural changes in binders used to prepare moulding and core sands. These changes may consist in the formation of new bonds, changes to their character or a transformation of the structure which may be accompanied, for example, by the destruction (disappearance) of some chemical bonds. They have a significant impact on the mechanical and technological properties of sands, but also on their environmental noxiousness or the ability to reclaim the sand. This article presents the results of infrared structural examinations of two furan resins and two binders produced based on those resins. Both pure resins and binders made of them were exposed to temperature. Changes taking place in their structure in the 25-200 °C temperature range were determined using infrared spectroscopy.

Downloads

Download data is not yet available.

References

Holtzer M. Światowe tendencje rozwojowe w zakresie mas formierskich i rdzeniowych pod kątem oddziaływania na środowisko, Przegląd Odlewnictwa, 3-4 (2011), 112-121

Lewandowski J.L.: Tworzywa na formy odlewnicze, Wydawnictwo Naukowe AKAPIT, Kraków, 1997

Psimenos A.Ch.: Kern- und Formteilfertigung mit No-Bake Bindemittelsystemen, Giesserei - Praxis, 4(2008), 111-119

Dańko R.: Badania regenerowalności zużytej masy formierskiej z żywicą furanową, XI Konferencja Techniczna Technical, 2008 (2008), 99-106

Paluszkiewicz C, Holtzer M., Bobrowslu A.: FTIR Analysis of Bentonites in Mould Sands, Journal of Mo-lecular Structure, 1-3 (2008), 109-114

Holtzer M., Bobrowski A., Grabowska B. Montmorillonite: a comparison of methods for its determination in foundry bentonites, Metalurgija, 50 (2011), 119-122

Bobrowski A., Holtzer M. Oznaczanie zawartości SiC>2 w piasku chromitowym metodą spektroskopii w podczerwieni, Archives of Foundry Engineering, 10 (2010) 2, 19-22

Badania nad wykorzystaniem spektroskopii w podczerwieni (FTIR) do analizy materiałów stosowanych w odlewnictwie. Projekt badawczy Nr N N507 370835. Okres realizacji (2008-2010)

Holtzer M., Bobrowski A., Żymankowska-Kumon S. Temperaturę influence on structural changes of foundry bentonites, Journal of Molecular Structure, 1004 (2011) 1-3, 102-108

Bobrowski A., Holtzer M:. Wykorzystanie spektroskopii w podczerwieni do badania materiałów stosowanych w odlewnictwie (Wysokojakościowe technologie odlewnicze, materiały i odlewy: monografia przygotowana z okazji XI międzynarodowej konferencji naukowej „Optymalizacja systemów produkcyjnych w odlewniach" pod red. Stanisława Pietrowskiego), Polska Akademia Nauk. Komisja Odlewnictwa. Ka-towice-Gliwice, s. 35-48

Renhe H, Hongmei G, Yaoji T., Qingyun L:. Curing mechanizm of furan resin modified with different agents and their thermal strength, Research&Development, 5 (2011), 161-165

Rosu D., Rosu L., Brebu M:. Thermal stability of silver sulfathiazole - epoxy resin network, Journal of Analytical and Applied Pyrolisys, 92 (2011), 10-18

Burket C.L., Rajagopalan R., Marencic A.P., Dronvajjala K., Foley H.C.: Genesis of porosity in polyfurfuryl alcohol derived nanoporous carbon, Carbon, 44 (2006), 2957-2963

Reghunadhan Nair C.P., Bindu R.L., Ninan K.N.: Thermal characteristics of addition-cure phenolic resins, Polymer Degradation and Stability, 73 (2001), 251-257

Gonzdlez R., Figueroa J.M., GonzdlezH.: Furfuryl alkohol polimerysation by iodine in methylene chloride, European Polymer Journal, 38 (2002), 287-297

Trick K.A., Saliba T.E.: Mechanisms of the pyrolysis of phenolic resin in a carbon/phenolic composite, Carbon, 33 (1995) 11, 1509-1515

Costa L., Rossi di Monterela L., Camino G, Weil E.D., Pearce E.M.: Structure charring relationship in phenol-formaldehyde type resins, Polymer Degradation and Stability, 56 (1997), 23-35

Liu ¥., Gao J., Zhang R. Thermal properties and stability of boron-containing phenol-formaldehyde resin formed from paraformaldehyde, Polymer Degradation and Stability, 77 (2002), 495-501

Downloads

Published

2012-06-30

How to Cite

Bobrowski, A., & Grabowska, B. (2012). THE IMPACT OF TEMPERATURE ON FURAN RESIN AND BINDER STRUCTURE. Metallurgy and Foundry Engineering, 38(1), 73. https://doi.org/10.7494/mafe.2012.38.1.73

Issue

Section

Articles

Most read articles by the same author(s)

1 2 > >>