Technological research of calcinated dolomite ores as intermediates for metal magnesium production

Alexandra Bekényiová; Zuzana Danková; Zuzana Kollová; Erika Fedorová; Pavel Bačo; Jaroslav Briančin; Katarína Čechovská

doi:10.7494/geol.2025.51.2.193

Authors

Alexandra Bekényiová State Geological Institute of Dionýz Štúr, Regional Centre Košice, Slovakia https://orcid.org/0000-0002-7313-6801
Zuzana Danková State Geological Institute of Dionýz Štúr, Regional Centre Košice, Slovakia https://orcid.org/0000-0002-5089-2479
Zuzana Kollová State Geological Institute of Dionýz Štúr, Regional Centre Košice, Slovakia https://orcid.org/0009-0009-4045-8706
Erika Fedorová State Geological Institute of Dionýz Štúr, Regional Centre Košice, Slovakia https://orcid.org/0000-0003-1709-2450
Pavel Bačo State Geological Institute of Dionýz Štúr, Regional Centre Košice, Slovakia https://orcid.org/0009-0000-5756-8076
Jaroslav Briančin Institute of Geotechnics, Slovak Academy of Sciences, Košice, Slovakia https://orcid.org/0000-0001-9195-507X
Katarína Čechovská State Geological Institute of Dionýz Štúr, Regional Centre Košice, Slovakia

DOI:

https://doi.org/10.7494/geol.2025.51.2.193

Keywords:

dolomite, annealing, calcined dolomite, DTA/TG analysis

Abstract

The current work investigates the differences between four types of calcinated dolomite samples as suitable intermediates for subsequent silicothermic reduction of metal magnesium by simultaneous differential thermal analysis (DTA) /thermogravimetric analysis (TG). The results of the DTA/TG analysis showed the least significant differences at the temperature endotherms with no weight loss on the TG curves at a temperature of 1373 K for the calcined dolomite sample TR-1 from Trebejov deposit. The most significant difference on the DTA curves was detected for the calcinated sample KRA-1 (deposit Kraľovany), which is connected with the hydration activity of the sample. According to the results of the chemical analyses, annealing products of all samples fulfilled two of the three conditions, namely a molecular ratio of CaO:MgO and an impurity content below 2.5% for their subsequent use as feedstocks in the silicothermal process for the preparation of metallic magnesium. Subsequently, the experimental test of silicothermic reduction of magnesium of calcinated sample ST-1 in a flowing argon atmosphere was investigated by EDX analysis. The results indicate that the prepared magnesium sample analysed by EDX – point and mapping analysis confirmed the presence of magnesium totalling 91% despite the failure to reach the temperature in the furnace required for the reduction of Mg.

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